Enhanced catalytic decomposition of a phosphate triester by modularly accessible bimetallic porphyrin dyads and dimers.
نویسندگان
چکیده
A series of metalloporphyrin dimers were modularly prepared and shown to catalyze the methanolysis of a phosphate triester, yielding rates that are large compared to the rate of the uncatalyzed reaction. Up to 1300-fold rate acceleration can be achieved via a combination of cavity-localized Lewis-acid activation and methoxide-induced methanolysis.
منابع مشابه
Enhanced catalytic decomposition of a phosphate triester by modularly accessible bimetallic porphyrin dyads and dimersw
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 35 شماره
صفحات -
تاریخ انتشار 2012